Bismuth is a chemical element that has atomic number 83 and has been given the chemical symbol Bi.
A trivalent poor metal, the chemistry of bismuth resembles arsenic
and antimony.
Elemental bismuth may occur naturally uncombined, although its sulfide and
oxide form important commercial ores. The free element is 86% as dense as lead, and brittle, with a silvery white color, and
often a pink tinge owing to the surface oxide. Bismuth metal has been known
from ancient times, although until the 18th century it was often
confused with lead and tin, which each have some of the metal's physical
properties. The name possibly comes from German words meaning "white mass
Detailed description
Bismuth is the
most naturally diamagnetic of all metals, and only mercury has a lower thermal
conductivity.
Bismuth has
classically been considered to be the heaviest naturally-occurring stable
element. Recently, however, it has been found to be very slightly radioactive:
its only non-synthetic isotope bismuth-209 decays via alpha decay into thallium-205 with a half-life of more than a billion times the estimated age
of the universe.[1]
Bismuth compounds
are used in cosmetics, medicines, and in medical procedures.
Bismuth has unusually low toxicity for a heavy metal. As the toxicity of lead has become more apparent in recent years,
alloy uses for bismuth metal, as a replacement for lead, have become an
increasing part of bismuth's commercial importance.
Characteristics
Physical characteristics
Bismuth is a
brittle metal with a white, silver-pink hue, often
occurring in its native form with an iridescent oxide tarnish showing many colors from
yellow to blue. The spiral stair stepped structure of a bismuth crystal is the result of a higher growth rate
around the outside edges than on the inside edges. The variations in the
thickness of the oxide layer that forms on the surface of the crystal causes
different wavelengths of light to interfere upon reflection, thus displaying a
rainbow of colors. When combusted with oxygen, bismuth burns with a blue flame and its oxide forms yellow fumes.[2] Its toxicity is much lower than that of its
neighbors in the periodic
table such as lead, tin, tellurium, antimony, and polonium.
Although ununpentium is theoretically more diamagnetic, no
other metal is verified to be more naturally
diamagnetic than bismuth. It is the most diamagnetic of naturally occurring
elements.[2] (Superdiamagnetism is a different physical phenomenon.)
Of any metal, it has the second lowest thermal
conductivity
(after mercury) and the highest Hall coefficient. It has a high electrical
resistance.[2] When deposited in sufficiently thin
layers on a substrate, bismuth is a semiconductor, rather than a poor metal.[3]
Occurrence
In the Earth's crust,
bismuth is about twice as abundant as gold. It is not usually
economical to mine it as a primary product. Rather, it is usually produced as a
byproduct of the processing of other metal ores, especially lead, tungsten (China), tin, copper, and also silver (indirectly) or
other metallic elements.
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