Mercury, also known as quicksilver or hydrargyrum, is a chemical
element with the symbol Hg (Latinized Greek:
hydrargyrum, from "hydr-"
meaning watery or runny and "argyros"
meaning silver) and atomic
number 80. A heavy, silvery d-block metal,
mercury is one of five metallic chemical elements that are liquid
at or near room temperature and pressure,[1][2]
the others being caesium, francium, gallium, and rubidium. Mercury is the only metal that is liquid at standard
conditions for temperature and pressure; the only other element that is
liquid under these conditions is bromine.[3]
With a melting point of −38.83 °C and boiling
point of 356.73 °C, mercury has one of the broadest ranges of its liquid
state of any metal.
Detailed description
Mercury occurs in
deposits throughout the world mostly as cinnabar (mercuric sulfide), which is the source of the red
pigment vermilion, and is mostly obtained by reduction
from cinnabar. Cinnabar is highly toxic by ingestion or inhalation of the dust.
Mercury
poisoning can also result
from exposure to soluble forms of mercury (such as mercuric chloride or methylmercury), inhalation of mercury vapor, or
eating fish contaminated with mercury.
Mercury is used
in thermometers, barometers, manometers, sphygmomanometers, float valves, some electrical switches, and other
scientific apparatus, though concerns about the element's toxicity have led to
mercury thermometers and sphygmomanometers being largely phased out in clinical
environments in favor of alcohol-filled, digital, or thermistor-based instruments. It remains in use
in a number of other ways in scientific and scientific research applications,
and in amalgam material for dental
restoration.
It is used in lighting: electricity passed through mercury vapor in a phosphor
tube produces short-wave ultraviolet light which then causes the phosphor to fluoresce, making visible light.
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Properties
Physical properties
Mercury is a
heavy, silvery-white metal. As compared to other metals, it is a poor conductor
of heat, but a fair conductor of electricity.[4]
Chemical properties
Mercury has an
exceptionally low melting temperature for a d-block metal. A complete
explanation of this fact requires a deep excursion into quantum physics, but it can be summarized as follows:
mercury has a unique electronic configuration where electrons fill up all the
available 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, 5s, 5p, 5d and 6s subshells.
As such configuration strongly resists removal of an electron, mercury behaves
similarly to noble gas elements, which form weak bonds and
thus easily melting solids. The stability of the 6s shell is due to the
presence of a filled 4f shell. An f shell poorly screens the nuclear charge
that increases the attractive Coulomb interaction of the 6s shell and the nucleus (see lanthanide
contraction).
The absence of a filled inner f shell is the reason for the much higher
melting temperature of cadmium. Metals such as gold have atoms with one less 6s electron than
mercury. Those electrons are more easily removed and are shared between the
gold atoms forming relatively strong metallic bonds.[2][5] At the melting point (−38.86 °C) its
density is[6] 14.1 g/cm3.
Reactivity and compounds
Mercury dissolves
to form amalgams with gold, zinc and many other
metals. Because iron is an exception, iron flasks have been traditionally used
to trade mercury. Other metals that do not form amalgams with mercury include
tantalum, tungsten and platinum. When heated, mercury also reacts with oxygen
in air to form mercury
oxide, which then can
be decomposed by further heating to higher temperatures.[7]
Since it is below
hydrogen in the reactivity
series of metals,
mercury does not react with most acids, such as dilute sulfuric acid, though oxidizing acids such as concentrated sulfuric acid and nitric acid or aqua regia dissolve it to give sulfate, nitrate, and chloride salts. Like silver, mercury reacts
with atmospheric hydrogen
sulfide. Mercury even
reacts with solid sulfur flakes, which are used in mercury spill kits to absorb
mercury vapors (spill kits also use activated carbon and powdered zinc).[7]
Mercury and aluminium
Mercury readily
combines with aluminium to form a mercury-aluminium amalgam when the two pure metals come into
contact. However, when the amalgam is exposed to air, the aluminium oxidizes,
leaving mercury behind. The oxide flakes away, exposing more mercury amalgam,
which repeats the process. This process continues until the supply of amalgam
is exhausted. Because this process releases mercury, a small amount of mercury
can "eat through" a large amount of aluminium over time, by
progressively forming amalgam and relinquishing the aluminium as oxide.[14]
Aluminium in air
is ordinarily protected by a molecule-thin layer of its own oxide, which is not
porous to oxygen. Mercury coming into contact with this oxide does no harm.
However, if any elemental aluminium is exposed (even by a recent scratch), the
mercury may combine with it, starting the process described above, and
potentially damaging a large part of the aluminium before it finally ends. For this reason, restrictions are
placed on the use and handling of mercury in proximity with aluminium. In
particular, mercury is not allowed aboard an aircraft under most circumstances
because of the risk of it forming an amalgam with exposed aluminium parts in
the aircraft.
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