Rutile is a mineral composed primarily of titanium dioxide, TiO2. Rutile has among the highest refractive indices at visible wavelengths of any known crystal, and also exhibits a
particularly large birefringence and high dispersion.
DETAILED
DESACRIPTION
Owing to these properties, it is useful for the manufacture of
certain optical elements, especially polarization optics, for longer
visible and infrared wavelengths up to
about 4.5μm.
Natural rutile may contain up to 10% iron and significant
amounts of niobium and tantalum. Rutile derives its
name from the Latinrutilus, red, in reference
to the deep red color observed in some specimens when viewed by transmitted
light.
Occurrence
Rutile is a common accessory mineral in
high-temperature and high-pressure metamorphic rocks and in igneous rocks.
Thermodynamically,
rutile is the most stable polymorph of TiO2 at all temperatures, exhibiting lower
total free energy than metastable phases of anatase or
brookite.[6] Consequently, the
transformation of the metastable TiO2 polymorphs to rutile is irreversible.
As it has the lowest molecular volume of the three main
polymorphs; it is generally the primary titanium bearing phase in most
high-pressure metamorphic rocks, chiefly eclogites.
Within the igneous environment, rutile is a common
accessory mineral in plutonic igneous rocks,
though it is also found occasionally in extrusive igneous rocks, particularly
those that have deep mantle sources such as kimberlites and lamproites. Anatase and
brookite are found in the igneous environment particularly as products of autogenic alteration during the cooling
of plutonic rocks; anatase is also found in placer deposits sourced from primary
rutile.
The occurrence of large specimen crystals is most
common in pegmatites, skarns, and granite greisens. Rutile is found as
an accessory mineral in some altered igneous rocks, and in certain gneisses and schists. In groups of
acicular crystals it is frequently
seen penetrating quartz as in the fléches d'amour from Graubünden, Switzerland. In 2005 the
Republic of Sierra Leone in West Africa had a production
capacity of 23% of the world's annual rutile supply, which rose to
approximately 30% in 2008. The reserves, lasting for about 19 years, are
estimated at 259,000,000 metric tons (285,000,000 short tons).
Uses and economic importance
In large enough quantities in beach sands, rutile forms an important constituent of heavy minerals and ore deposits. Miners
extract and separate the valuable minerals—e.g., rutile, zircon, and ilmenite. The main uses for
rutile are the manufacture of refractory ceramic, as a pigment, and for the
production of titanium metal.
Finely powdered rutile is a brilliant white pigment
and is used in paints, plastics, paper, foods, and other applications that call for a bright white
color. Titanium dioxide pigment is the
single greatest use of titanium worldwide. Nanoscale particles of rutile are
transparent to visible light but are highly
effective in the absorption of ultraviolet radiation. The UV
absorption of nano-sized rutile particles is blue-shifted compared to bulk
rutile, so that higher-energy UV light is absorbed by the nanoparticles. Hence, they are
used in sunscreens to protect against
UV-induced skin damage.
Small rutile needles present in gems are responsible for
an optical phenomenon known as asterism. Asteriated gems
are known as "star" gems. Star sapphires, star rubies, and other "star" gems are highly sought after and
are generally more valuable than their normal counterparts.
Rutile is widely used as a welding electrode covering.
It is also used as a part of the ZTR index, which classifies
highly weathered sediments.
Rutile, as a large band-gap semiconductor, has in recent
decades been the subject of significant research towards applications as a
functional oxide for applications in photocatalysis and dilute magnetism.
Research efforts typically utilize small quantities of synthetic rutile rather
than mineral-deposit derived materials.
PRICE
$10.195/KG
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